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23 Mar 2013

FUEL DISTILLATION


Single stage distillation uses a single column which works at atmospheric pressure.

·        Crude oil is pre-heated and then fed to pipe still heater
·        Fraction are distilled of according to their boiling points
·        Side streams are further distilled in small column called stripper
·        In stripper steam is used to manage the temperature for more volatile liquids

Disadvantages:

  • Capacity is limited
  • High B.P products cannot be separated because of cracking

This process is also called crude tropping or atmospheric distillation

Two stage distillation includes two columns

  • Primary column operates at 3- atm pressure
  • Secondary column operates at atmospheric pressure


  • These are working together with a stabliser
  • 2 or 3 side streams are withdrawn from primary column (e.g. gasoline, naphtha etc.)
  • Overhead product is fed to secondary stabliser
  • Remaining fractions are separated in secondary column (e.g. kerosene oil, diesel oil etc.)

Three stage distillation consists of three columns i.e. pressure, atmospheric and vaccum columns

  • Residue of atmospheric column is preheated at 425oC and fed to vaccum column which works at 30-80 atm pressure
  • High boiling liquids are separated in vaccum column because B.P is reduced at lower pressure (e.g. lubricating oil, asphalt and heavy gas oil)
  • Vaccum tower is similar to that of atmospheric tower but its diameter is larger due to larger crude vapour volume
  • Steam jet ejectors or barometric condensers are used to maintain desired vaccum

Gaseous fuels are those fuels which burnt in gaseous state to produce heat

Advantages:

  • Absence of mineral impurities
  • Consistency in quality and convenience
  • Efficiency in use
  • Least costly on industrial level

Important gaseous fuels are:

  • Natural gas          
  • Methane from coal mines
  • Coal bed methane
  • Wood gas
  • Gobar gas
  • Sewage gas
  • Liquefied petroleum gas (LPG)

Producer gas comprise CO, N2 produced in a furnace

  • In simple gas producer, dry air is blown through a bed of coal at sufficiently high temperature
  • In result of series of reactions gas is produced
  • Steam is mixed with air to moderate temperature to reduce clinker formation

L.D converter gas is a mixture of CO and CO2 and is produced in L.D converter in steel making process

  • When O2  is blown to L.D converter to remove carbon from pig iron then gas is produced
  • In former converters it contained 80% CO
  • To remove CO it is burnt and CO is produced
  • In modern steel converters gas is recovered at mouth cooled and stored for use