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23 Mar 2013

Liberation


Liberation is the release of the valuable mineral from the gangue.

·        Major objective of comminution process
·        By liberation energy can be saved in further processing
·        High liberation is essential, if high grade solids are required
·        For leaching, it is necessary to expose  the required mineral only
·        In practical, complete liberation is seldom achieved
·        Particles of “locked” mineral and gangue are called middlings

Degree of liberation  is the %age of mineral occurring as free particles in the ore in relation to the total content.

  • If there are weak boundaries between mineral and gangue then there will be high degree of liberation
  • If adhesion is strong then this produces much middlings and low degree of liberation
  • To increase the degree of liberation involves directing the breaking stresses at the mineral crystal boundaries
  • Degree of liberation is zero when valuable mineral is completely enclosed with gangue

Methods of liberation:

Froth flotation requires as much as possible mineral surface to be exposed

·        Most important and versatile mineral processing technique
·        Developed in 1906
·        Permitted for low grade, uneconomic minerals
·        Used only for specific minerals e.g. lead-zinc, copper-zinc etc.

Principle:

It uses the difference in surface properties of mineral and gangue

·        It is a physico-chemical process
·        It involves three phases with many sub processes
1.     selective attachment to air bubbles or true flotation
2.     entrainment in the water which passes through the froth
3.     physical entrapment between particles in froth attached to air bubbles referred as aggregation
·         separation efficiency is dependent on the degree of entrainment and physical entrapment
·         Process can only be applied to fine particles

Chemical leaching requires a portion of mineral must be exposed to provide a channel to the bulk of mineral

Classification is a process of separation of particles on the basis of velocity with which they fall in a fluid.

·        Fluid is usually water
·        Applied to such a particles which are too fine
·        Velocity of particles is dependent on size, specific gravity and shape of particles
·        If resistance of fluid is high and velocity of particles is low then it is called viscous flow
·        When velocity is high and resistance is low then it is called turbulent flow
·        Free settling is sinking of particles in a larger volume of liquid than that of particles
·        Particles are not apparent in free settling
·        When solid particles increased in pulp and particle crowding become apparent then that is called hindered settling

Magnetic separation used the difference in magnetic properties of to separate the valuable mineral and gangue

·        There are two types of magnetic materials:
1.     Diamagnetic materials are repelled along the lines of force to a point where field intensity is smaller
·        Cannot be concentrated magnetically
1.     Paramagnetic materials are attracted along the magnetic lines of forces to points of greater field intensity